Solar hydrogen production with cerium oxides thermochemical cycle

This paper discusses the hydrogen production using a solar driven thermochemical cycle. The thermochemical cycle is based on nonstoichiometric cerium oxides redox and the solar concentration system is a solar dish. Detailed optical and redox models were developed to optimize the hydrogen production performance as function of several design parameters (i.e. concentration ratio, reactor pressures and temperatures) The efficiency of the considered technology is compared against two commercially available technologies namely PV + electrolyzer and Dish Stirling + electrolyzer. Results show that solar-to-fuel efficiency of 21.2% can be achieved at design condition assuming a concentration ratio around 5000, reduction and oxidation temperatures of 1500°C and 1275 °C. When moving to annual performance, the annual yield of the considered approach can be as high as 16.7% which is about 43% higher than the best competitive technology. The higher performance implies that higher installation costs around 40% can be accepted for the innovative concept to achieve the same cost of hydrogen

Simulation of Oxygen Transport Membranes for CPO Reactors in Small-scale Hydrogen or Syngas Production Applications

The proposed work aims at presenting a 1D finite volume steady state simulation model of an Oxygen Transport Membrane for Catalytic Partial Oxidation (OTM-CPO) reactor developed at the Group of Energy COnversion Systems (GECOS) at Politecnico di Milano. The model is able to simulate supported and unsupported perovskite-based reactive membranes by means of a lumped mass and energy transport method; the active ceramic layer is modelled throughout a generalised O2permeation equation, which depends on the micro-structure characteristics and mixed-ion conduction properties of the material. The supporting porous structure is represented by a mass diffusion model dominated by gas-gas, porous and surface exchange transport processes. The model also includes a global chemical reaction kinetic mechanism of CPO on Rh-based catalysts. The model is applied to simulate the behaviour of a membrane reactor operated upstream the Hydrogen Transport Membrane for Methane Steam Reforming (HTM-MSR) installed at the Laboratory of Micro-Cogeneration (LMC) at Politecnico di Milano. The test bench is focused on testing fuel pre-processing systems for low temperature fuel cells (PEM) applications. The simulation object of this work would allow obtaining a feasibility assessment of the system and a preliminary design of the OTM-CPO reactor

Membrane reactors for green hydrogen production from biogas and biomethane:A techno-economic assessment

This work investigates the performance of a fluidized-bed membrane reactor for pure hydrogen production. A techno-economic assessment of a plant with the production capacity of 100 kgH2/day was carried out, evaluating the optimum design of the system in terms of reactor size (diameter and number of membranes) and operating pressures. Starting from a biomass source, hydrogen production through autothermal reforming of two different feedstock, biogas and biomethane, is compared. Results in terms of efficiency indicates that biomethane outperforms biogas as feedstock for the system, both from the reactor (97.4% vs 97.0%) and the overall system efficiency (63.7% vs 62.7%) point of views. Nevertheless, looking at the final LCOH, the additional cost of biomethane leads to a higher cost of the hydrogen produced (4.62 €/kgH2@20 bar vs 4.39 €/kgH2@20 bar), indicating that at the current price biogas is the more convenient choice.</p

Green Hydrogen Production from Raw Biogas: A Techno-Economic Investigation of Conventional Processes Using Pressure Swing Adsorption Unit

This paper discusses the techno-economic assessment of hydrogen production from biogas with conventional systems. The work is part of the European project BIONICO, whose purpose is to develop and test a membrane reactor (MR) for hydrogen production from biogas. Within the BIONICO project, steam reforming (SR) and autothermal reforming (ATR), have been identified as well-known technologies for hydrogen production from biogas. Two biogases were examined: one produced by landfill and the other one by anaerobic digester. The purification unit required in the conventional plants has been studied and modeled in detail, using Aspen Adsorption. A pressure swing adsorption system (PSA) with two and four beds and a vacuum PSA (VPSA) made of four beds are compared. VPSA operates at sub-atmospheric pressure, thus increasing the recovery: results of the simulations show that the performances strongly depend on the design choices and on the gas feeding the purification unit. The best purity and recovery values were obtained with the VPSA system, which achieves a recovery between 50% and 60% at a vacuum pressure of 0.1 bar and a hydrogen purity of 99.999%. The SR and ATR plants were designed in Aspen Plus, integrating the studied VPSA model, and analyzing the behavior of the systems at the variation of the pressure and the type of input biogas. The SR system achieves a maximum efficiency, calculated on the LHV, of 52% at 12 bar, while the ATR of 28% at 18 bar. The economic analysis determined a hydrogen production cost of around 5 €/kg of hydrogen for the SR case

Experimental and Numerical Study of a Micro-cogeneration Stirling Engine for Residential Applications☆

Abstract Micro-cogeneration Stirling engines are considered promising for residential applications. The present work covers the experimental and numerical analysis of a commercial Stirling unit capable of 8 kW of hot water and 1 kW of electricity. A previously concluded experimental campaign that focused on external measurements is extended here to include internal measurements. The scope is collecting useful data to validate a detailed numerical model. Three test cases are considered by fixing the temperature of the cogeneration water at the unit inlet at alternatively: 30, 50 and 70 °C. Mass flow rate of the water is kept at the nominal value of 0.194 kg/s. This numerical model is an extension of the well-known work by Urieli and Berchowitz. The model is calibrated on the 50 °C case and compared in the other two cases. Maximum deviations with respect to experiments are about 4% on net power output, whereas they remain below 1% on heat input and rejection. The Stirling unit has shown an electrical efficiency exceeding slightly 9% and a thermal efficiency of 90% (both based on the Higher Heating Value) if the cogeneration water inlet temperature is 30 °C, which decreases down to about 84% with water inlet at 70 °C. The Primary Energy Index is remarkably positive for all cases, ranging from 17% to 22% as the temperature of the water inlet goes from 70 °C to 30 °C

Experimental and numerical study of a micro-cogeneration Stirling unit under diverse conditions of the working fluid

Micro-cogeneration Stirling units are promising for residential applications because of high total efficiencies, favorable ratios of thermal to electrical powers and low CO as well as NOx emissions. This work focuses on the experimental and the numerical analysis of a commercial unit generating 8 kW of hot water (up to 15 kW with an auxiliary burner) and 1 kW of electricity burning natural gas. In the experimental campaign, the initial pressure of the working fluid is changed in a range from 9 to 24 barg – 20 barg being the nominal value – while the inlet temperature of the water loop and its mass flow rate are kept at the nominal conditions of, respectively, 50°C and 0.194 kg/s. The experimental results indicate clearly that the initial pressure of the working fluid – Nitrogen – affects strongly the net electrical power output and efficiency. The best performance for the output and efficiency of 943 W and 9.6% (based on the higher heating value of the burnt natural gas) are achieved at 22 barg. On the other hand, the thermal power trend indicates a maximum value of 8420 W at the working pressure of 24 barg, which corresponds to a thermal efficiency of 84.7% (again based on higher heating value). Measurements are coupled to a detailed model based on a modification of the work by Urieli and Berchowitz. Thanks to the tuning with the experimental results, the numerical model allows investigating the profiles of the main thermodynamic parameters and heat losses during the cycle, as well as estimating those physical properties that are not directly measurable. The major losses turn to be the wall parasitic heat conduction from heater to cooler and the non-unitary effectiveness of the regenerator

Modeling and Testing of a Micro-cogeneration Stirling Engine Under Diverse Conditions of the Working Fluid

Abstract Micro-cogeneration Stirling engines are promising for residential applications. This work focuses on the experimental and numerical analyses of a commercial unit generating 8 kW of hot water and 1 kW of electricity burning natural gas. Measurements are coupled to a detailed model based on a modification of Urieli and Berchowitz's work. The results indicate that the thermal efficiency is influenced by the water loop inlet temperature, varying from 90% at 30 °C to 84% at 70 °C (HHV-based). The measured and simulated powers of the engine are in the 900-964 W range depending on the water temperature and differ by less than 4%. Net electric efficiency of the engine is 15% and of the whole cogeneration unit above 9% (HHV-based). Helium instead of Nitrogen as working fluid is expected to increase the performance